Zheng Haoquan - Postdoc - Stockholm University LinkedIn

CRYSTALLINE SILICA - Avhandlingar.se

Although silica nanoparticles are used as building blocks in nature and synthetic mesostructures, the influence of nanoparticle characteristics on the assembly and disassembly of mesostructured A catalyst containing small (ca. 2.5 nm) and crystalline Pt nanoparticles embedded into the walls of a mesostructured silica framework was found to be highly active in alkene hydrosilylation reaching TONs of ca. 105. More importantly, no Pt leaching was detected.

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2009-01-01 2017-07-01 2012-11-15 Mesoporous silica nanoparticles (MSNs) have garnered a great deal of attention as potential carriers for therapeutic payloads. Here, we report a pH-responsive drug-carrier based on chondroitin sulfate functionalized mesostructured silica nanoparticles (NMChS-MSNs) ie, the amidation between NMChS macromer and amino group functionalized MSNs. 2014-12-21 2017-07-01 Mesoporous silica nanoparticles are promising materials for drug delivery and other biomedical applications because they are nontoxic and can be taken up by living cells. Through appropriate design and synthesis, multifunctional mesoporous silica nanoparticles for sophisticated bio‐applications are … Silica, mesostructured (MCM-41) is a part of low-density organized mesoporous silicate system which has a 2D hexagonal phase, prepared in the presence of quaternary ammonium halide surfactant. It has ordered and large pores with diameter in the range 1.5-10 nm and specific surface area of 1500 m 2 /g. Although silica nanoparticles are used as building blocks in nature and synthetic mesostructures, the influence of nanoparticle characteristics on the assembly and disassembly of mesostructured A catalyst containing small (ca. 2.5 nm) and crystalline Pt nanoparticles embedded into the walls of a mesostructured silica framework was found to be highly active in alkene hydrosilylation reaching TONs of ca.

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At a low con-centration (<100 μg/mL), LP-MSN-P has low cytotoxicity. Moreover, we also demonstrate that the LP-MSN-P can effectively deliver siRNA into cancer cells and silence the oncogenes.

CRYSTALLINE SILICA - Avhandlingar.se

nanoparticles was obtained using octane as a hydrophobic support and styrene mesostructured silica particles, moreover in the reduction of the particle size  9 Oct 2012 Chondroitin sulfate functionalized mesostructured silica nanoparticles as biocompatible carriers for drug delivery Juqun Xi,1 Jin Qin,2 Lei  23 Mei 2017 Poly-L-lysine Functionalized Large Pore Cubic Mesostructured Silica Nanoparticles as Biocompatible Carriers for Gene Delivery. Hartono  10 Aug 2016 A series of Ni incorporated Mesostructured Silica Nanoparticles (MSN) were prepared by physical mixing method.

Here, we developed perfluorocarbon-loaded ultraporous mesostructured silica nanoparticles (PERFUMNs) as 19 F MRI detectable oxygen-sensing probes. Ultraporous mesostructured silica nanoparticles (UMNs) have large internal cavities (average = 1.8 cm 3 g –1 ), facilitating an average 17% loading efficiency of PFCs, meeting the threshold fluorine concentrations needed for imaging studies. Ultraporous mesostructured silica nanoparticles. Sam M. Egger, Katie R. Hurley, Ashish Datt, Garrett Swindlehurst, Christy L. Haynes.
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2017-07-01 · Core-shell hierarchical mesostructured silica nanoparticles for gene and chemodrug co-delivery in sequence: We have successfully developed a “chemical homology” strategy for the fabrication of core-shell hierarchical mesostructured MSNs (H-MSNs) with different-sized mesopores and composition-varied frameworks separately in the core and shell. 2014-12-21 · Pyrene confined mesostructured silica nanoparticles were prepared using a facile one-pot method where pyrene molecules were first encapsulated in the hydrophobic parts of cetyltrimethylammonium micelles and then silica polymerized around these micelles. The resulting hybrid particles have sizes of around 75 nm with fairly good size distribution. Although silica nanoparticles are used as building blocks in nature and synthetic mesostructures, the influence of nanoparticle characteristics on the assembly and disassembly of mesostructured 2013-08-21 · Controlling the morphology and pore size of mesostructured silica nanoparticles: the role of the iron oxidation state.

The physicochemical properties of catalysts were investigated by several techniques, including N2 physisorption measurements, powder X-ray diffraction, N2 The surface of α-Fe2O3 nanoparticles was successfully coated with mesostructured silica templated by surfactant assemblies using cetyltrimethylammonium ions. By repeating the coating operation, it was possible to control the thickness of the mesostructured silica phase. Cell-penetrating peptide together with PEG-modified mesostructured silica nanoparticles promotes mucous permeation and oral delivery of therapeutic proteins and peptides† Xinyi Tan , a Yan Zhang , b Qian Wang , ae Tianyang Ren , a Jingxin Gou , a Wei Guo , c Tian Yin , d Haibing He ,* a Yu Zhang a and Xing Tang * a confined mesostructured silica nanoparticles. In order to confine pyrene molecules in mesostructured silica nano-particles, we firstly dissolved hydrophobic pyrene molecules in water using the cetyltrimethylammonium bromide (CTAB) surfactant. Pyrene molecules were encapsulated in the hydro-phobic inner parts of the rod-shaped surfactant micelles.
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Together they form a unique fingerprint. hexadecyldimethylamine Chemical Compounds Poor permeation across intestinal mucous barriers often limits the oral delivery of prospective therapeutic proteins and peptides (TPPs). In order to address this issue, cell penetrating peptide (CPP) together with PEG modified and pore-enlarged mesostructured silica nanoparticle (NP) were constructed to form the mucus-penetrating electrostatic Rose Bengal (RB), a xanthene dye, incorporated into mesostructured silica nanoparticles (MSNs) exhibits efficient singlet oxygen (1 O 2) generation when illuminated with 540 nm green light which is particularly promising for PDT applications.Several systems with different RB loadings were synthesized and fully characterized by means of spectroscopic techniques in combination with a Here, we developed perfluorocarbon-loaded ultraporous mesostructured silica nanoparticles (PERFUMNs) as 19 F MRI detectable oxygen-sensing probes. Ultraporous mesostructured silica nanoparticles (UMNs) have large internal cavities (average = 1.8 cm 3 g -1 ), facilitating an average 17% loading efficiency of PFCs, meeting the threshold fluorine concentrations needed for imaging studies. Dual type Fe species (isomorphously substituted Fe species and a colloidal α-FeOOH (IS-FeOOH)) supported on mesostructured silica nanoparticles (IS-FeOOH/MSN) were prepared by a simple electrochemical method followed by impregnation.

The N 2 physisorption results indicated that the introduction of Ni altered markedly the surface properties of MCM-41 and MSN. Mesoporous silica nanoparticles (MSNs) are silica nanoparticles with pores that range in diameter from 2 to 50 nm and have an overall diameter below 1 µm. Their range of pore sizes is consistent with the IUPAC definition of mesoporous1 and make them ideal materials for applications ranging from catalysis and environmen This work investigated the possibility of incorporation of nickel into several mesostructured cellular foam (MCF) silica supports prepared at various aging times (1, 2, and 3 days) by using deposition-precipitation method followed by reducetion process and to look for the best support to obtain supported nickel catalyst with highest nickel loading and smallest size of nickel nanoparticles. Multistep Organic Transformations over Base‐Rhodium/Diamine‐Bifunctionalized Mesostructured Silica Nanoparticles Hang Liao Key Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key, Laboratory of Rare Earth Functional Materials, Shanghai Normal University, No.100 Guilin Rd., 200234 Shanghai Shi, P.R. China), Fax: (+86) 216-432-280 Highly active Ni-promoted mesostructured silica nanoparticles for CO 2 methanation P. Triwahyono IntroductionRecycling of CO 2 as a carbon source for chemicals and fuels should be considered as a more sustainable use of resources which may indeed lead to reduced consumption of carbon-based fossil resources without producing more CO 2 from the whole system. Abstract: Mesoporous silica nanoparticles (MSNs) have garnered a great deal of attention as potential carriers for therapeutic payloads.
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Jan van Stam Karlstad University

hexadecyldimethylamine Chemical Compounds Poor permeation across intestinal mucous barriers often limits the oral delivery of prospective therapeutic proteins and peptides (TPPs). In order to address this issue, cell penetrating peptide (CPP) together with PEG modified and pore-enlarged mesostructured silica nanoparticle (NP) were constructed to form the mucus-penetrating electrostatic Rose Bengal (RB), a xanthene dye, incorporated into mesostructured silica nanoparticles (MSNs) exhibits efficient singlet oxygen (1 O 2) generation when illuminated with 540 nm green light which is particularly promising for PDT applications.Several systems with different RB loadings were synthesized and fully characterized by means of spectroscopic techniques in combination with a Here, we developed perfluorocarbon-loaded ultraporous mesostructured silica nanoparticles (PERFUMNs) as 19 F MRI detectable oxygen-sensing probes. Ultraporous mesostructured silica nanoparticles (UMNs) have large internal cavities (average = 1.8 cm 3 g -1 ), facilitating an average 17% loading efficiency of PFCs, meeting the threshold fluorine concentrations needed for imaging studies. Dual type Fe species (isomorphously substituted Fe species and a colloidal α-FeOOH (IS-FeOOH)) supported on mesostructured silica nanoparticles (IS-FeOOH/MSN) were prepared by a simple electrochemical method followed by impregnation. Characterization was conducted using X-ray diffraction, transmission electron micr Herein, we took advantage of a BF 4 − anion hydrogen bonding strategy to anchor a chiral cationic rhodium/diamine complex within base‐functionalized mesostructured silica nanoparticles conveniently to construct a bifunctional heterogeneous catalyst.